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- W2006220104 abstract "Three fungal metabolites with a common structural feature as prenylated phenols were synthesized in their naturally occurring and optically active forms: ascochlorin [(2'E,4'E,1'R,2'R,6'R)-(-)-5-chloro-2,4-dihydroxy-6-methyl-3-[5'-(1',2',6'-trimethyl-3'-oxo-cyclohexyl)-3'-methyl-2', 4'-pentadienyl] benzaldehyde], ascofuranone [(2'E,6'E,1'S)-(-)-5-chloro-2, 4-dihydroxy-6-methyl-3-[7'-(3',3'-dimethyl-4'-oxo-2'-oxacyclopentyl)-3',7'-dimethyl -2', 6'-heptadienyl] benzaldehyde] and ascofuranol [(2'E,6'E,1'S,4'S)-(-)-5-chloro-2,4-dihydroxy-6-methyl-3-[7'-(3', 3'-dimethyl-4'-hydroxy-2'-oxacyclopentyl)-3', 7'-dimethyl-2',6'-hepta-dienyl]benzaldehyde ]. (+)-Ascofuranone and (+)-ascofuranol were also synthesized. By the present synthesis the absolute configuration of the natural (-)-ascofuranol was established as (1'S,4'S)." @default.
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- W2006220104 date "1985-01-01" @default.
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- W2006220104 title "Synthesis of the natural enantiomers of ascochlorin, ascofuranone and ascofuranol" @default.
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- W2006220104 doi "https://doi.org/10.1016/s0040-4020(01)96657-8" @default.
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