Matches in SemOpenAlex for { <https://semopenalex.org/work/W2006221347> ?p ?o ?g. }
- W2006221347 endingPage "201" @default.
- W2006221347 startingPage "167" @default.
- W2006221347 abstract "The synthesis, characterization, and applications of five-coordinate group 13 compounds are examined and surveyed. The range of compounds covered in this study includes those with five separate ligands (called “Class A”), a single bidentate ligand (Class B), two bidentate ligands (Class C), tridentate ligand coordination (Class D), and tetradentate ligand coordination (Class E). Each class of five-coordinate compounds is further sub- divided into the possible “Types” of structures that may be envisioned to occur. Following an extensive (although not exhaustive) search of the literature it was found that the majority of the compounds fell into a very few Types in each Class. Thus, future reviews may focus more specifically on the details within these well-populated Types. Many of the possible Types of compounds had no members whatsoever, and thus provide clear targets for future research endeavors. As a striking example, no compound involving a single five-coordinate ligand (Class F) was found. The ultimate goal of this work is to provide a systematic understanding of the types of five-coordinate compounds that have been made and that may be sought in the future. As such it is primarily a survey of the known compounds with some details about their structures. In particular, the distinction between trigonal bipyramidal and square pyramidal geometry will be discussed in terms of a literature measure known as the “tau” value. This value ranges from “0” for square pyramidal to “1” for trigonal bipyramidal geometries, thus providing a quantitative indication of what geometry a structure most closely adopts." @default.
- W2006221347 created "2016-06-24" @default.
- W2006221347 creator A5001601382 @default.
- W2006221347 creator A5006633633 @default.
- W2006221347 creator A5066796969 @default.
- W2006221347 date "2003-01-01" @default.
- W2006221347 modified "2023-09-27" @default.
- W2006221347 title "Compounds Containing Five-Coordinate Group 13 Elements" @default.
- W2006221347 cites W1964282952 @default.
- W2006221347 cites W1965323171 @default.
- W2006221347 cites W1972978162 @default.
- W2006221347 cites W1973505400 @default.
- W2006221347 cites W1973590451 @default.
- W2006221347 cites W1974315027 @default.
- W2006221347 cites W1975949634 @default.
- W2006221347 cites W1977264258 @default.
- W2006221347 cites W1977484732 @default.
- W2006221347 cites W1978263959 @default.
- W2006221347 cites W1978314874 @default.
- W2006221347 cites W1979333598 @default.
- W2006221347 cites W1980425602 @default.
- W2006221347 cites W1981821689 @default.
- W2006221347 cites W1985450812 @default.
- W2006221347 cites W1986609487 @default.
- W2006221347 cites W1986624405 @default.
- W2006221347 cites W1991957105 @default.
- W2006221347 cites W1992546414 @default.
- W2006221347 cites W1992806235 @default.
- W2006221347 cites W1993086113 @default.
- W2006221347 cites W1993351198 @default.
- W2006221347 cites W1993628662 @default.
- W2006221347 cites W1996371859 @default.
- W2006221347 cites W1997876950 @default.
- W2006221347 cites W2000470292 @default.
- W2006221347 cites W2000963540 @default.
- W2006221347 cites W2001902778 @default.
- W2006221347 cites W2003956391 @default.
- W2006221347 cites W2004172020 @default.
- W2006221347 cites W2004629443 @default.
- W2006221347 cites W2005480853 @default.
- W2006221347 cites W2006954895 @default.
- W2006221347 cites W2008255957 @default.
- W2006221347 cites W2013733288 @default.
- W2006221347 cites W2015806434 @default.
- W2006221347 cites W2018274136 @default.
- W2006221347 cites W2018347834 @default.
- W2006221347 cites W2021648154 @default.
- W2006221347 cites W2022361250 @default.
- W2006221347 cites W2028738961 @default.
- W2006221347 cites W2029002932 @default.
- W2006221347 cites W2030429876 @default.
- W2006221347 cites W2030556848 @default.
- W2006221347 cites W2031253748 @default.
- W2006221347 cites W2031548301 @default.
- W2006221347 cites W2032295988 @default.
- W2006221347 cites W2033677055 @default.
- W2006221347 cites W2035417911 @default.
- W2006221347 cites W2037705055 @default.
- W2006221347 cites W2040757118 @default.
- W2006221347 cites W2045073128 @default.
- W2006221347 cites W2050006124 @default.
- W2006221347 cites W2053968757 @default.
- W2006221347 cites W2055052323 @default.
- W2006221347 cites W2056100150 @default.
- W2006221347 cites W2056207921 @default.
- W2006221347 cites W2057213185 @default.
- W2006221347 cites W2057438319 @default.
- W2006221347 cites W2059397713 @default.
- W2006221347 cites W2060803033 @default.
- W2006221347 cites W2062695524 @default.
- W2006221347 cites W2063522661 @default.
- W2006221347 cites W2064284002 @default.
- W2006221347 cites W2064376534 @default.
- W2006221347 cites W2066137514 @default.
- W2006221347 cites W2074155359 @default.
- W2006221347 cites W2074739136 @default.
- W2006221347 cites W2081872262 @default.
- W2006221347 cites W2085799663 @default.
- W2006221347 cites W2094223245 @default.
- W2006221347 cites W2095148352 @default.
- W2006221347 cites W2102125860 @default.
- W2006221347 cites W2105249240 @default.
- W2006221347 cites W2113882249 @default.
- W2006221347 cites W2136608836 @default.
- W2006221347 cites W2139859082 @default.
- W2006221347 cites W2152034645 @default.
- W2006221347 cites W2152058774 @default.
- W2006221347 cites W2159250584 @default.
- W2006221347 cites W2160920522 @default.
- W2006221347 cites W2327722441 @default.
- W2006221347 cites W2474579450 @default.
- W2006221347 cites W2949289551 @default.
- W2006221347 cites W2949711881 @default.
- W2006221347 cites W2950666645 @default.
- W2006221347 cites W2951399512 @default.
- W2006221347 cites W4231951464 @default.
- W2006221347 cites W4253544700 @default.
- W2006221347 doi "https://doi.org/10.1007/3-540-46110-8_5" @default.