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- W2006223503 abstract "(1-Methylene-2-propenyl)cobaloxime (1), a diene having a transition metal substituent, was prepared conveniently from 2-chloromagnesio-1,3-butadiene and chlorocobaloxime. Cobaloxime 1 gives Diels–Alder adducts with olefinic dienophiles (maleic anhydride, N-phenylmaleimide, p-benzoquinone, dimethyl fumarate, methyl vinyl ketone, and methyl acrylate) and acetylenic dienophiles (methyl propiolate and dimethyl acetylenedicarboxylate). The reactivity of cobaloxime 1 is higher than that of its metalloid analogs, such as 2-silyl-, 2-seleno-, and 2-stannyl-1,3-butadiene, though the reaction pattern is essentially the same. This additional activation of the diene system by cobaloxime is accounted for by a back donation of the filled d-orbital of cobalt(III) to the π-system of the diene." @default.
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- W2006223503 date "1992-05-01" @default.
- W2006223503 modified "2023-10-12" @default.
- W2006223503 title "Diels–Alder Reaction of (1-Methylene-2-propenyl)cobaloxime, 1-Methylene-2-propenyl-bis(dimethylglyoximato)pyridine-cobalt(III)" @default.
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- W2006223503 doi "https://doi.org/10.1246/bcsj.65.1252" @default.
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