FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2006234763> ?p ?o ?g. }

• W2006234763 endingPage "211" @default.
• W2006234763 startingPage "199" @default.
• W2006234763 abstract "The adsorption and desorption processes of a new series of redox-active transition metal complexes of the type [Os(bpy)2Cl(Py(CH2)nSH)](PF6), with n = 4, 6, or 9, capable of forming adsorbed monolayers on gold and platinum electrodes have been studied using cyclic voltammetry. The adsorption behavior of these osmium thiol complexes appears to be consistent with the Freundlich model. Although more than one equivalent layer of the osmium complex was deposited, the multilayer was found to be porous. Variations in the pH of the deposition solutions from pH 1 to pH 5, as well as variations in the ionic strength of the supporting electrolyte, had no effect on the amount of complex deposited. However, variations in the ionic strength of the supporting electrolyte gave rise to changes in the formal potential of the osmium redox couple which were ascribed to charge screening and Donnan effects. The desorption reaction was described by a simple exponential expression. From the temperature dependence of the desorption rate and the Arrhenius relationship, the activation energies for the desorption processes were determined. The activation energies were found to be dependent on both the length of the alkyl chain and the solvent used during desorption. In addition, it was determined that after an ‘annealing’ time of 24 to 48 h there was a reorganization of the deposited multilayer to a lower energy form with a corresponding 20% increase in the activation energy for desorption, indicative of the multilayer reorganizing into a lower energy, more stable configuration." @default.
• W2006234763 created "2016-06-24" @default.
• W2006234763 creator A5042053197 @default.
• W2006234763 creator A5082048815 @default.
• W2006234763 date "1996-05-01" @default.
• W2006234763 modified "2023-10-14" @default.
• W2006234763 title "Adsorption-desorption processes of redox-active osmium thiol monolayers" @default.
• W2006234763 cites W1965447629 @default.
• W2006234763 cites W1970652124 @default.
• W2006234763 cites W1972091231 @default.
• W2006234763 cites W1977398427 @default.
• W2006234763 cites W1982302115 @default.
• W2006234763 cites W1985170759 @default.
• W2006234763 cites W1989367423 @default.
• W2006234763 cites W1994247387 @default.
• W2006234763 cites W2008104733 @default.
• W2006234763 cites W2009034769 @default.
• W2006234763 cites W2010042379 @default.
• W2006234763 cites W2011254969 @default.
• W2006234763 cites W2013918333 @default.
• W2006234763 cites W2024452928 @default.
• W2006234763 cites W2025152938 @default.
• W2006234763 cites W2028027229 @default.
• W2006234763 cites W2033405137 @default.
• W2006234763 cites W2039702409 @default.
• W2006234763 cites W2042022091 @default.
• W2006234763 cites W2045041374 @default.
• W2006234763 cites W2047330812 @default.
• W2006234763 cites W2048953414 @default.
• W2006234763 cites W2053062943 @default.
• W2006234763 cites W2054836251 @default.
• W2006234763 cites W2056648038 @default.
• W2006234763 cites W2059690474 @default.
• W2006234763 cites W2064627969 @default.
• W2006234763 cites W2064665785 @default.
• W2006234763 cites W2069099100 @default.
• W2006234763 cites W2072892216 @default.
• W2006234763 cites W2074944968 @default.
• W2006234763 cites W2077697112 @default.
• W2006234763 cites W2083783900 @default.
• W2006234763 cites W2084813134 @default.
• W2006234763 cites W2089622237 @default.
• W2006234763 cites W2091408549 @default.
• W2006234763 cites W2091518202 @default.
• W2006234763 cites W2092298304 @default.
• W2006234763 cites W2095330438 @default.
• W2006234763 cites W2238695478 @default.
• W2006234763 doi "https://doi.org/10.1016/0022-0728(96)04518-4" @default.
• W2006234763 hasPublicationYear "1996" @default.
• W2006234763 type Work @default.
• W2006234763 sameAs 2006234763 @default.
• W2006234763 citedByCount "21" @default.
• W2006234763 crossrefType "journal-article" @default.
• W2006234763 hasAuthorship W2006234763A5042053197 @default.
• W2006234763 hasAuthorship W2006234763A5082048815 @default.
• W2006234763 hasConcept C113196181 @default.
• W2006234763 hasConcept C145148216 @default.
• W2006234763 hasConcept C147789679 @default.
• W2006234763 hasConcept C150394285 @default.
• W2006234763 hasConcept C161790260 @default.
• W2006234763 hasConcept C162711632 @default.
• W2006234763 hasConcept C17525397 @default.
• W2006234763 hasConcept C178790620 @default.
• W2006234763 hasConcept C179104552 @default.
• W2006234763 hasConcept C184651966 @default.
• W2006234763 hasConcept C185592680 @default.
• W2006234763 hasConcept C187428577 @default.
• W2006234763 hasConcept C2182769 @default.
• W2006234763 hasConcept C2777869211 @default.
• W2006234763 hasConcept C52859227 @default.
• W2006234763 hasConcept C540285154 @default.
• W2006234763 hasConcept C55493867 @default.
• W2006234763 hasConcept C555196967 @default.
• W2006234763 hasConcept C55904794 @default.
• W2006234763 hasConcept C68801617 @default.
• W2006234763 hasConcept C7070889 @default.
• W2006234763 hasConcept C86183883 @default.
• W2006234763 hasConcept C95121573 @default.
• W2006234763 hasConceptScore W2006234763C113196181 @default.
• W2006234763 hasConceptScore W2006234763C145148216 @default.
• W2006234763 hasConceptScore W2006234763C147789679 @default.
• W2006234763 hasConceptScore W2006234763C150394285 @default.
• W2006234763 hasConceptScore W2006234763C161790260 @default.
• W2006234763 hasConceptScore W2006234763C162711632 @default.
• W2006234763 hasConceptScore W2006234763C17525397 @default.
• W2006234763 hasConceptScore W2006234763C178790620 @default.
• W2006234763 hasConceptScore W2006234763C179104552 @default.
• W2006234763 hasConceptScore W2006234763C184651966 @default.
• W2006234763 hasConceptScore W2006234763C185592680 @default.
• W2006234763 hasConceptScore W2006234763C187428577 @default.
• W2006234763 hasConceptScore W2006234763C2182769 @default.
• W2006234763 hasConceptScore W2006234763C2777869211 @default.
• W2006234763 hasConceptScore W2006234763C52859227 @default.
• W2006234763 hasConceptScore W2006234763C540285154 @default.
• W2006234763 hasConceptScore W2006234763C55493867 @default.
• W2006234763 hasConceptScore W2006234763C555196967 @default.
• W2006234763 hasConceptScore W2006234763C55904794 @default.
• W2006234763 hasConceptScore W2006234763C68801617 @default.

• next