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- W2006237906 abstract "The high sensitivity of 15N shielding to the displacement of the lone pair electrons makes it a useful conformational probe for remote parts of a conjugated molecule. Thus, the chemical shifts are observed for different rotamers of enaminones in the slow exchange limit. The interpretation of the 15N chemical shifts in terms of the non-planarity of the E, s-E rotamers is in accord with 13C chemical shifts and 1J(CH) coupling constants." @default.
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- W2006237906 modified "2023-09-26" @default.
- W2006237906 title "15N chemical shifts as a conformational probe in enaminones A variable temperature study at natural isotope abundance" @default.
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- W2006237906 doi "https://doi.org/10.1002/mrc.1270170418" @default.
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