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- W2006245197 abstract "The diffusion of Ag in amorphous As/sub 2/S/sub 3/ and As/sub 2/Se/sub 3/ at 175/sup 0/C is accompanied with the reduction of As from a valence of +3 to +2 and +2 to +1 to maintain charge neutrality in the glass. The reactions for the sulfide and selenide glasses are identical. Ag/sup +/ alone diffuses at this temperature, all other ions are essentially immobile. An amorphous reaction product phase is formed in the diffusion zone with a composition range of 28.6 to 44.4 atomic percent Ag. The lower limit corresponds to all As cations of +2 valence (amorphous Ag/sub 2/As/sub 2/S/sub 3/). The upper limit, the maximum solubility of Ag in these glasses, corresponds to all As cations of +1 valence (amorphous Ag/sub 4/As/sub 2/S/sub 3/). The diffusivity of Ag in these glasses at 175/sup 0/C in the concentration range of 10 to 35 atomic percent Ag is: Sulfide--4 x 10/sup -14/ exp(+0.23 +- .01) (atomic % Ag), Selenide--2 x 10/sup -12/ exp(+0.14 +- .01) (atomic % Ag)." @default.
- W2006245197 created "2016-06-24" @default.
- W2006245197 creator A5033203611 @default.
- W2006245197 date "1977-09-01" @default.
- W2006245197 modified "2023-09-23" @default.
- W2006245197 title "Reactions and diffusion in the silver--arsenic chalcogenide glass system" @default.
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- W2006245197 doi "https://doi.org/10.2172/5346095" @default.
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