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- W2006270010 abstract "The transfer mechanism of Ni2+, Co2+ Zn2+ and Cd2+ ions from an aqueous to a dichloroethane (DCE) solution of phenanthroline derivatives (Phen) was studied. Included were 1,10-phenanthroline (phen), 4,7-dimethyl-1,10-phenanthroline (4,7-DMP), 4,7-diphenyl-1,10-phenanthroline (4,7-DPP) and 2,9-dimethyl-1,10-phenanthroline (2,9-DMP). The investigation was carried out by current-scan polarography at the ascending water electrode (AWE). Some polarographic waves were observed that can be attributed to the slow formation of 1:1 M2+-Phen complexes. In some cases, as with the Ni2+-Phen systems and the Co2M,7-DPP system, no wave was observed, because the complexation rates are too slow. All of the Cd2+-Phen and all of the Zn2+-Phen systems, except for the Zn2M,7-DPP system which exhibits a kinetic wave, yielded diffusion-controlled waves. Furthermore, a number of these systems appear to be affected by significant interfacial adsorption of the M2+-Phen complexes." @default.
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- W2006270010 date "1991-04-01" @default.
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- W2006270010 title "Ion-Transfer Current-Scan Polarographic Studies of Metal Extractants with Ascending Water Electrode: Transfer of Divalent Metal Ion Complexes of Phenanthrolines across a Liquid-Liquid Interface" @default.
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- W2006270010 doi "https://doi.org/10.2116/analsci.7.313" @default.
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