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- W2006275554 abstract "The absorption rate and mechanism of NO2-N2O4 gas mixtures diluted with nitrogen into nitric acid solutions were investigated in a wetted wall column at 20 °C and 30 °C. It was found that N2O4, which is continuously in equilibrium with NO2, is preferentially absorbed into diluted nitric acid as well as into concentrated nitric acid. The absorption of N2O4 into diluted acid is accompanied by a rapid pseudo-first order reaction with water. Values of HN2O4 were measured as a function of the acid strength at 20 °C. Above 63% nitric acid the absorption was found to be purely physical. The solubility of N2O4 into concentrated nitric acid (63%) was derived from total vapour pressure data concerning the system NO2-N2O4-H2O-HNO3. It was found that Henry's law was valid within the condition considered." @default.
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- W2006275554 title "Absorption of NO2/N2O4 into diluted and concentrated nitric acid" @default.
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- W2006275554 doi "https://doi.org/10.1016/0300-9467(82)80013-0" @default.
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