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• W2006276502 abstract "Abstract Reactions of a racemic amine with chiral, N α ‐acetylated, C α ‐methyl l ‐phenylglycine‐based dipeptide 5(4 H )‐oxazolones proceed diastereoselectively to give predominantly dipeptide alkylamides comprising d ‐α‐phenylethylamine. Diastereoselectivity is remarkably sensitive to solvent polarity and reaction temperature but not significantly to the nature of the C α ‐tetrasubstituted α‐amino acid at position 1 of the dipeptide. The β‐turn 3D structures of the aminolysis products were established in CDCl 3 solution by FT‐IR absorption and in one case in the crystal state by X‐ray diffraction as well. © 2005 Wiley‐Liss, Inc. Chirality 17:481–487, 2005." @default.
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• W2006276502 date "2005-01-01" @default.
• W2006276502 modified "2023-10-11" @default.
• W2006276502 title "Stereoselective acylation of a racemic amine with C^α‐methyl phenylglycine‐based dipeptide 5(4<i>H</i>)‐oxazolones" @default.
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• W2006276502 doi "https://doi.org/10.1002/chir.20182" @default.
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