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- W2006281738 abstract "‘Three-electron bond’ and ‘increased-valence’ formulae are described for NO, O2, NO3, O3 and NO2. These species occur in the Heicklen and Cohen mechanism for the atmospheric oxidation of nitric oxide to nitrogen dioxide. By using these valence formulae, O2 is predicted to be formed as the 3Σ−g electronic state in the reaction NO + O3 → NO2+O2. Similar conclusions pertain for the reaction HO+O3 → HO2+O2, and for some other radical transfer reactions which involve the formation of O2. Use of NO as a Lewis base in the NO/O3 reaction can generate O2 either as 1Σ+g or as 1Δg." @default.
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- W2006281738 title "Valence formulae and the oxidation of nitric oxide to nitrogen dioxide" @default.
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- W2006281738 doi "https://doi.org/10.1016/0022-2860(72)85217-7" @default.
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