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• W2006283449 endingPage "7774" @default.
• W2006283449 startingPage "7768" @default.
• W2006283449 abstract "[CrIIIF(NCMe)5](BF4)2·MeCN (1) was synthesized from a prolonged dissolution of [CrIII(NCMe)6](BF4)3 in MeCN via fluoride abstraction from BF4−. Complex 1 exhibits a crystal field splitting, Δo, of 17 470 cm−1 and is a nonaqueous source of CrIIIF2+. The reaction of 1 with (NEt4)3[CrIII(CN)6] formed a new Prussian-blue-like magnetic material of (NEt4)0.04[CrIIIF]1.54[CrIII(CN)6](BF4)0.12·0.10(MeCN) (2) composition. Complex 2 magnetically orders at a critical temperature, Tc, of 85 K and at 2 K exhibits magnetic hysteresis with a coercive field, Hcr, of 60 Oe and a remanent magnetization, Mrem, of 1880 emuOe/mol." @default.
• W2006283449 created "2016-06-24" @default.
• W2006283449 creator A5008130628 @default.
• W2006283449 creator A5055587168 @default.
• W2006283449 creator A5056844262 @default.
• W2006283449 creator A5057803757 @default.
• W2006283449 creator A5079379110 @default.
• W2006283449 date "2008-08-07" @default.
• W2006283449 modified "2023-09-26" @default.
• W2006283449 title "Structure and Properties of [Cr^IIIF(NCMe)₅](BF₄)₂·MeCN: A Nonaqueous Source of Cr^IIIF²⁺ and a Building Block for New Prussian-Blue-Like Magnetic Materials" @default.
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• W2006283449 doi "https://doi.org/10.1021/ic800837f" @default.

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