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- W2006302579 abstract "The structural and magnetic features of the TbCo4M compounds (M = Al and Ga) have been studied by means of neutron powder diffraction and magnetic measurements. X-ray diffraction experiments show that the samples are single phased, crystallizing in the CaCu5-type structure. Neutron powder diffraction measurements demonstrate a preferential substitution of Al and Ga at the 3g crystallographic site of the CaCu5-type structure. Together with neutron powder diffraction investigations, magnetization measurements and x-ray powder diffraction studies performed on field-oriented samples are combined in order to clarify the effects of the Al and Ga substitutions on the magnetic features of these compounds. The modifications of the magnetic properties upon substitution are significant: a drastic decrease of the mean Co magnetic moment and of the Curie temperature is observed. Unlike what was found earlier for TbCo5, no sign of a spin reorientation transition has been observed in the present TbCo4M compounds. Moreover, both compounds present a planar magnetocrystalline anisotropy over the whole temperature range. Finally, the thermal evolutions of the magnetization of terbium and cobalt sublattices in TbCo4Al and TbCo4Ga are presented." @default.
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- W2006302579 date "2002-10-18" @default.
- W2006302579 modified "2023-09-25" @default.
- W2006302579 title "Neutron diffraction and magnetic investigations of the TbCo<sub>4</sub>M compounds (M Al and Ga)" @default.
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- W2006302579 doi "https://doi.org/10.1088/0953-8984/14/43/318" @default.
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