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- W2006324110 abstract "The crystal structure of (CH3NH3)2MnCl4 (MAMC) is determined by neutron diffraction at 188 K in the low temperature tetragonal phase (P42/ncm). The sequence of structural phase transitions of MAMC can be discussed in terms of NH …︁ Cl bridges between NH3 and certain Cl−-ions. The order of the room temperature orthorhombic structure is determined by one dominant H-bond and that of the low temperature tetragonal structure by three equivalent H-bridges. Mit Hilfe der Neutronenbeugung wird die Kristallstruktur von (CH3NH3)2MnCl4 (MAMC) bei 188 K in der tetragonalen Tieftemperaturphase (P42/ncm) bestimmt. Die Folge der strukturellen Phasenübergänge von MAMC kann entsprechend den NH …︁ Cl Brücken zwischen NH3 und bestimmten Cl−-Ionen diskutiert werden. Die Ordnung der orthorhombischen Zimmertemperaturstruktur wird durch eine dominante H-Bindung bestimmt und diejenige der tetragonalen Tieftemperaturstruktur durch drei gleichwertige H-Brücken." @default.
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- W2006324110 title "On the importance of hydrogen bonding for the structural phase transitions in (CH3NH3)2MnCl4. A single-crystal neutron diffraction study" @default.
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- W2006324110 doi "https://doi.org/10.1002/pssa.2210350225" @default.
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