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- W2006339189 abstract "An antioxidant, 1-(3‘,4‘-dihydroxycinnamoyl)cyclopentane-2,3-diol [or (E)-2,3-dihydroxycyclopentyl-3-(3‘,4‘-dihydroxyphenyl)acrylate (1)], and two known trans- and cis-chlorogenic acid methyl esters were isolated from the ethanolic extract of the leaves of Chimarrhis turbinata. The relative configuration of 1 was determined by NMR and by comparison of the circular dichroic spectrum (CD) with those of the enantiomers of synthetic 3‘,4‘-dimethoxycinnamoyl analogues. The absolute configuration of one of the synthetic enantiomers was determined using the CD exciton chirality method. This established the structure of naturally occurring 1 as (E)-2,3-dihydroxycyclopentyl-3-(3‘,4‘-dihydroxyphenyl)acrylate." @default.
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- W2006339189 date "2006-06-13" @default.
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- W2006339189 title "The Absolute Configuration of 1-(3‘,4‘-Dihydroxycinnamoyl)cyclopentane-2,3-diol from the Amazonian Tree <i>Chimarrhis </i><i>t</i><i>urbinata</i>" @default.
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- W2006339189 doi "https://doi.org/10.1021/np050522y" @default.
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