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• W2006348247 abstract "The formation and scission of the imidazolate- bridge linkage in the binuclear copper(II) complex with glycylglycine ([GlyGlyCuIIIm−CuIIGlyGly]−, GlyGly = glycylglycinate(2-), Im− = imidazolate- (1-)) were studied in aqueous solutions as a function of pH. Potentiometric titration and electron spin resonance spectroscopy showed that the binuclear complex was formed in the range 9.8 < pH < 11.5. The bridge was broken by protonation at lower pH to give rise to two kinds of mononuclear complexes, [GlyGlyCuIIH2O] and [GlyGlyCuIIImH] (ImH= imidazole). The equilibrium constant was 7.46 × 10−5 mol dm−3. Above pH 11.5, the bridge in the binuclear complex was broken by hydroxide ion to give rise to [GlyGlyCuIIOH−]− and [GlyGlyCuII- Im−]−. The coordinated imidazolate of the latter complex was not displaced by hydroxide ion even under conditions of high pH." @default.
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• W2006348247 date "1987-04-01" @default.
• W2006348247 modified "2023-09-27" @default.
• W2006348247 title "Formation and scission of the imidazolate-bridge linkage in binuclear copper(II) complex with glycylglycine as a function of pH in aqueous solution" @default.
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• W2006348247 doi "https://doi.org/10.1016/s0020-1693(00)85561-9" @default.
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