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- W2006353485 abstract "The Diels–Alder reaction of various pyrimidine ortho-quinodimethanes generated in situ with C60 gives access to a variety of new fullerodihydroquinazoline derivatives. This variety is increased since substituents on the pyrimidine ring can be easily modified before or after its reaction with C60. Variable temperature 1H NMR spectra provided thermodynamic parameters related to the boat-to-boat interconversion of the cyclohexene ring fused to the fullerene moiety. The mass spectra of the prepared cycloadducts show that the retro-Diels–Alder process takes place easily with elimination of the corresponding diene molecule." @default.
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- W2006353485 date "2009-07-01" @default.
- W2006353485 modified "2023-10-18" @default.
- W2006353485 title "Pyrimidine ortho-quinodimethanes. Part 2: Synthesis of new [60]fullerene adducts based on substituted pyrimidine derivatives and their 1H NMR dynamic study" @default.
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- W2006353485 doi "https://doi.org/10.1016/j.tet.2009.05.026" @default.
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