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- W2006353889 abstract "A new family of three-legged piano stool structured organometallic compounds containing the fragment η 5 -cyclopentadienyl-ruthenium(II)/iron(II) has been synthesized to evaluate the existence of electronic metal to ligand charge transfer upon coordination of the novel benzodithiophene ligands (BDT), benzo[l,2-b;4,3-b']dithiophen -2-carbonitrile (L1) and benzo[1,2 -b;4,3-b']dithiophen -2'nitro-2-carbonitrile (L2). All the compounds were characterized by 1 H, 13 C, 31 P NMR, IR and UV-Vis. spectroscopies and their electrochemistry studied by cyclic voltammetry. The X-ray structures of [Ru(η 5 -C 5 H 5 )(PPh 3 ) 2 -(NCC 10 H 5 S 2 )][PF 6 l (IRu), [Ru(η 5 -C 5 H 5 )(PPh3)2(NCC 10 H 5 S 2 )][CF 3 SO 3 ] (1'Ru), [Ru(η 5 H 5 )(DPPE)(NCC 10 -H 5 S 2 )][PF 6 ] 2Ru and [Fe(η 5 -C 5 H 5 )(DPPE)(NCC 10 H 5 S 2 )][PF 6 ] (2Fe) were determined by X-ray diffraction showing centric crystallization on groups PI and P2 1/n , respectively. Quadratic hyperpolarizabilities (β) of some of the complexes (2Fe, 2Ru and 3Fe) have been determined by hyper-Rayleigh scattering (HRS) measurements at a fundamental wavelength of 1500 nm, to minimize the probability of fluorescence due to two-photon absorption and to reduce the effect of resonance enhancement, in order to estimate static β values." @default.
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- W2006353889 date "2008-09-01" @default.
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- W2006353889 title "Synthesis of organometallic Ru(II) and Fe(II) complexes containing fused rings hemi-helical ligands as chromophores. Evaluation of non-linear optical properties by HRS" @default.
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- W2006353889 doi "https://doi.org/10.1016/j.jorganchem.2008.05.035" @default.
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