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- W2006359984 abstract "Abstract A study of the physical and chemical changes during processing in MOD-derived YBCO films was performed. Fully processed films were 70–85% of theoretical density. The sintering rate increased substantially in the compositional range F/Ba = 1.8–1.5. The activation energy for sintering decreased above a P(H 2 O) dependent threshold temperature. XRD indicated this temperature/composition threshold also corresponded to YBCO nucleation, suggesting ex situ YBCO forms in contact with a melt. The ramp rate and P(H 2 O) were used to control F/Ba trajectories, which were correlated to performance. The nucleation of YBCO was strongly dependent on processing conditions. Nucleation temperature was varied by at least 60 °C in the study. The optimal YBCO nucleation temperature in the 300–800 nm films was around 725 °C. a -axis grains dominated the microstructures of films where YBCO nucleated at a -axis grains, were found when the nucleation temperature was >750 °C." @default.
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- W2006359984 date "2006-12-01" @default.
- W2006359984 modified "2023-10-18" @default.
- W2006359984 title "Trajectory-property relationships in MOD-derived YBCO films" @default.
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- W2006359984 doi "https://doi.org/10.1016/j.physc.2006.08.011" @default.
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