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- W2006367908 abstract "A densely packed 1ifmmodetimeselsetexttimesfi{}1-O overlayer with an oxygen coverage of 1.0 (relative to the number of substrate surface atoms) was prepared on Ru(0001) by sequential dissociation of ${mathrm{O}}_{2}$ and ${mathrm{NO}}_{2}$ and studied by means of high-resolution electron-energy-loss spectroscopy. Two dipole-active modes were observed at 81 and 7.3 meV due to a ${ensuremath{nu}}_{mathrm{ensuremath{perp}}}$(Ru-O) stretch mode and a new surface mode, respectively. The value of ${ensuremath{nu}}_{mathrm{ensuremath{perp}}}$(Ru-O) is shifted to higher energy compared to that for the known 2ifmmodetimeselsetexttimesfi{}2-O and 2ifmmodetimeselsetexttimesfi{}1-O adlayers at smaller oxygen coverages. These measurements indicate that the ${mathrm{O}}_{2}$ dissociation is kinetically hindered for oxygen coverages larger than 0.5." @default.
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- W2006367908 title "Vibrational analysis of the 1×1-O overlayer on Ru(0001)" @default.
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- W2006367908 doi "https://doi.org/10.1103/physrevb.55.4751" @default.
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