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- W2006390817 abstract "The most stable conformations of some protonated tertiary carboxylic acids in HF-BF3 and HF-SbF5 have been shown to be those which have one OH proton syn and the other anti to the alkyl groups. In HF solutions, the intramolecular interconversions between the two degenerate conformations is much faster with tertiary than with secondary or primary carboxylic acids; with the tertiary acids it is likely to proceed via the trans-trans rather than the cis-cis con-former as an intermediate. The conformational equilibration of protonated pivalic acid is much faster in HF solution than in FSO3H-SbF5-SO2ClF solution." @default.
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- W2006390817 date "2010-09-02" @default.
- W2006390817 modified "2023-10-18" @default.
- W2006390817 title "Structure and conformational equilibration of protonated tertiary alkanoic acids in HF solution" @default.
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- W2006390817 doi "https://doi.org/10.1002/recl.19730921002" @default.
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