FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2006407303> ?p ?o ?g. }

• W2006407303 endingPage "783" @default.
• W2006407303 startingPage "783" @default.
• W2006407303 abstract "Reaction between cis- or trans-[Co(en)2CI2]+(en = ethane-1,2-diamine) and D-glucosamine (2-amino-2-deoxy-D-glucopyranose) in neutral aqueous solution results in a very complicated product mixture including as a major component several isomeric complex ions in which the co-ordination sphere is formally made up of two ethane-1,2-diamine units and one sugar unit. Separation of these complexes by ion-exchange chromatography, and subsequent spectroscopic and structural studies have shown that they are diastereomeric forms in which the co-ordination sphere actually contains one bidentate ethane-1,2-diamine chelate and a multidentate ligand which is an N-(2′-aminoethyl)amino-substituted glycosylamine derived from glucosamine, fructosamine or mannosamine. The presence of the fructosamine moiety reveals that the complex formation reaction is accompanied by the Amadori rearrangement of glucosamine, while the presence of the mannosamine moiety indicates that this rearrangement may be reversible and possibly stereospecific in particular diastereoisomers. Crystal structure determinations have definitively characterised eight of the reaction products as: 1 a complex of the 1-N-(2′-aminoethyl)amino-substituted glucosamine in which the sugar, although chelated to the metal as part of a tridentate ligand, is in its open-chain form and in which the four nitrogen atoms derived from the original two ethane-1,2-diamine units are essentially coplanar; 2 a complex of tridentate 1-N-(2′-aminoethyl)amino-substituted glucosamine in which the sugar has its pyranose form and the chelate edges spanned by the original ethane-1,2-diamine units are in the Δ configuration; 3 a complex of 1-N-(2′-aminoethyl)amino-substituted glucosamine in which the sugar is in its open-chain form and the ligand is bound in a quadridentate manner, with the chelate edges spanned by the original ethane-1,2-diamine units in the Δ configuration; 4 a complex of 1-N-(2′-aminoethyl)amino-substituted mannosamine in which the sugar has a furanose form and is part of a quadridentate ligand, and the chelate edges spanned by the original ethane-1,2-diamine units are in the Δ configuration; 5 a complex of quadridentate 1-(2′-aminoethylamino)-1-deoxy-fructopyranosylamine in which the chelate edges spanned by the original ethane-1,2-diamine units are in the Δ configuration; 6 a complex of quadridentate 1-(2′-aminoethylamino)-1-deoxy-fructopyranosylamine in which the chelate edges spanned by the original ethane-1,2-diamine units are in the Δ configuration; 7 the same complex as 6 but in the form where its co-ordinated sugar hydroxyl group is deprotonated; and 8 a complex of 1-(2′-aminoethylamino)-1-deoxyfructopyranosylamine in which the chelate edges spanned by the original ethane-1,2-diamine units are in the Δ configuration." @default.
• W2006407303 created "2016-06-24" @default.
• W2006407303 creator A5021731130 @default.
• W2006407303 creator A5029773183 @default.
• W2006407303 creator A5032455471 @default.
• W2006407303 creator A5059696902 @default.
• W2006407303 creator A5082369913 @default.
• W2006407303 date "1995-01-01" @default.
• W2006407303 modified "2023-10-14" @default.
• W2006407303 title "Metal complexes of carbohydrates: isolation and characterisation of cobalt(III) complexes containing N-substituted glycosylamine ligands derived from ethane-1,2-diamine and glucosamine" @default.
• W2006407303 cites W1966672762 @default.
• W2006407303 cites W1974355266 @default.
• W2006407303 cites W1990645302 @default.
• W2006407303 cites W2003459891 @default.
• W2006407303 cites W2006419173 @default.
• W2006407303 cites W2011988112 @default.
• W2006407303 cites W2030685895 @default.
• W2006407303 cites W2042762916 @default.
• W2006407303 cites W2043837116 @default.
• W2006407303 cites W2051001540 @default.
• W2006407303 cites W2052710618 @default.
• W2006407303 cites W2093175133 @default.
• W2006407303 cites W2093846346 @default.
• W2006407303 cites W2094289331 @default.
• W2006407303 cites W2105686863 @default.
• W2006407303 cites W2117086217 @default.
• W2006407303 cites W2313210074 @default.
• W2006407303 cites W2326280754 @default.
• W2006407303 cites W2329120083 @default.
• W2006407303 cites W2949139991 @default.
• W2006407303 cites W3138955298 @default.
• W2006407303 cites W968790055 @default.
• W2006407303 doi "https://doi.org/10.1039/dt9950000783" @default.
• W2006407303 hasPublicationYear "1995" @default.
• W2006407303 type Work @default.
• W2006407303 sameAs 2006407303 @default.
• W2006407303 citedByCount "16" @default.
• W2006407303 countsByYear W20064073032014 @default.
• W2006407303 crossrefType "journal-article" @default.
• W2006407303 hasAuthorship W2006407303A5021731130 @default.
• W2006407303 hasAuthorship W2006407303A5029773183 @default.
• W2006407303 hasAuthorship W2006407303A5032455471 @default.
• W2006407303 hasAuthorship W2006407303A5059696902 @default.
• W2006407303 hasAuthorship W2006407303A5082369913 @default.
• W2006407303 hasConcept C115624301 @default.
• W2006407303 hasConcept C116569031 @default.
• W2006407303 hasConcept C138716334 @default.
• W2006407303 hasConcept C155647269 @default.
• W2006407303 hasConcept C161790260 @default.
• W2006407303 hasConcept C170493617 @default.
• W2006407303 hasConcept C178516000 @default.
• W2006407303 hasConcept C178790620 @default.
• W2006407303 hasConcept C185592680 @default.
• W2006407303 hasConcept C187921627 @default.
• W2006407303 hasConcept C188027245 @default.
• W2006407303 hasConcept C197404232 @default.
• W2006407303 hasConcept C2776568683 @default.
• W2006407303 hasConcept C2778125326 @default.
• W2006407303 hasConcept C2780728571 @default.
• W2006407303 hasConcept C2780871995 @default.
• W2006407303 hasConcept C55493867 @default.
• W2006407303 hasConcept C71240020 @default.
• W2006407303 hasConceptScore W2006407303C115624301 @default.
• W2006407303 hasConceptScore W2006407303C116569031 @default.
• W2006407303 hasConceptScore W2006407303C138716334 @default.
• W2006407303 hasConceptScore W2006407303C155647269 @default.
• W2006407303 hasConceptScore W2006407303C161790260 @default.
• W2006407303 hasConceptScore W2006407303C170493617 @default.
• W2006407303 hasConceptScore W2006407303C178516000 @default.
• W2006407303 hasConceptScore W2006407303C178790620 @default.
• W2006407303 hasConceptScore W2006407303C185592680 @default.
• W2006407303 hasConceptScore W2006407303C187921627 @default.
• W2006407303 hasConceptScore W2006407303C188027245 @default.
• W2006407303 hasConceptScore W2006407303C197404232 @default.
• W2006407303 hasConceptScore W2006407303C2776568683 @default.
• W2006407303 hasConceptScore W2006407303C2778125326 @default.
• W2006407303 hasConceptScore W2006407303C2780728571 @default.
• W2006407303 hasConceptScore W2006407303C2780871995 @default.
• W2006407303 hasConceptScore W2006407303C55493867 @default.
• W2006407303 hasConceptScore W2006407303C71240020 @default.
• W2006407303 hasIssue "5" @default.
• W2006407303 hasLocation W20064073031 @default.
• W2006407303 hasOpenAccess W2006407303 @default.
• W2006407303 hasPrimaryLocation W20064073031 @default.
• W2006407303 hasRelatedWork W1990810923 @default.
• W2006407303 hasRelatedWork W2004468053 @default.
• W2006407303 hasRelatedWork W2028422424 @default.
• W2006407303 hasRelatedWork W2036698888 @default.
• W2006407303 hasRelatedWork W2046603791 @default.
• W2006407303 hasRelatedWork W2049457259 @default.
• W2006407303 hasRelatedWork W2053357505 @default.
• W2006407303 hasRelatedWork W2069588159 @default.
• W2006407303 hasRelatedWork W2077471112 @default.
• W2006407303 hasRelatedWork W2951526589 @default.
• W2006407303 isParatext "false" @default.
• W2006407303 isRetracted "false" @default.
• W2006407303 magId "2006407303" @default.
• W2006407303 workType "article" @default.