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- W2006445853 abstract "Reaction of iron powder with 1,3,4,7-tetramethylisoindole at 350° affords the square planar complex octamethyl-tetrabenzporphyriniron(II), whose magnetic moment indicates a spin quintet ground state. Mössbauer measurements at 4.2°K in an applied magnetic field of 50 kG show that the electric field gradient at iron is positive and axially symmetric, consistent with a 5B2g ground term. The bistetrahydrofuran adduct is also high spin, whereas the bispyridine adduct is diamagnetic with 1A1g ground state. Comparisons are made with data for the related tetraphenylporphiniron(II) and phthalocyanineiron(II) derivatives." @default.
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- W2006445853 date "1974-04-01" @default.
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- W2006445853 title "Electronic ground state of iron in octamethyltetrabenzporphyriniron(II), a new square planar ferrous porphyrin" @default.
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- W2006445853 doi "https://doi.org/10.1016/0009-2614(74)85378-9" @default.
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