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- W2006467422 abstract "Chronoamperometry and electrochemical impedance spectroscopy were employed to determine the diffusion coefficients in the solid state Ds for anions HSO4− (from H2SO4 in three protic solvents) and ClO4− (from LiClO4 in three aprotic solvents), which are intercalated in graphite. Strong convection in the electrolyte was provided to minimize the time constant for the transport in the electrolyte diffusion layer. Ds ≈ 10−5 and 10−6 cm2 s−1 were found for these categories. The Walden products η · Ds were identified to be constant (η = specific viscosity in the bulk liquid). It is concluded, that the anions move in the solid in an environment which is similar to the liquid electrolyte due to cointercalation of solvent molecules." @default.
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- W2006467422 date "1995-09-01" @default.
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- W2006467422 title "Transport of intercalated anions in graphite according to Walden's rule" @default.
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- W2006467422 doi "https://doi.org/10.1016/0013-4686(94)00329-y" @default.
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