FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2006485019> ?p ?o ?g. }

• W2006485019 endingPage "1130" @default.
• W2006485019 startingPage "1123" @default.
• W2006485019 abstract "The possibility of using zeolites containing the 2,4,6-triphenylpyrylium cation as photocatalysts for the degradation of pollutants has been tested on aqueous xylidine (2,4-dimethylaniline) solutions as models for contaminated wastewaters. The influence of the photocatalyst and substrate concentrations on xylidine oxidation has been investigated in homogeneous solution, by performing a series of experiments chosen according to the experimental design methodology (Doehlert uniform array). The empirical models and the corresponding response surfaces obtained from data analysis have been used for simulating and predicting degradation efficiency. The results have shown that conversion increases with increasing amounts of photocatalyst and decreasing concentration of the model pollutant. The fluorescence of 2,4,6-triphenylpyrylium was quenched by xylidine with a rate constant k(q) of 3.1x10(9)M(-1)s(-1). This result suggests a direct electron transfer between the excited pyrylium salt and xylidine. Because of the limited stability of the photocatalyst in homogeneous media, a pyrylium containing Y-zeolite has been tested for the photocatalytic oxidation of xylidine under heterogeneous conditions. The results suggest that the supported catalyst has a much improved stability and that xylidine oxidation rates remain nearly constant during the whole reaction time. An additional advantage of the pyrylium containing zeolite photocatalyst is that it can be recycled and used for further experiments." @default.
• W2006485019 created "2016-06-24" @default.
• W2006485019 creator A5001364873 @default.
• W2006485019 creator A5031648040 @default.
• W2006485019 creator A5032971728 @default.
• W2006485019 creator A5048246567 @default.
• W2006485019 creator A5058846543 @default.
• W2006485019 creator A5062941929 @default.
• W2006485019 creator A5063663504 @default.
• W2006485019 date "2004-12-01" @default.
• W2006485019 modified "2023-10-17" @default.
• W2006485019 title "Oxidative degradation of 2,4-xylidine by photosensitization with 2,4,6-triphenylpyrylium: homogeneous and heterogeneous catalysis" @default.
• W2006485019 cites W1965248004 @default.
• W2006485019 cites W1965721664 @default.
• W2006485019 cites W1989122752 @default.
• W2006485019 cites W1991855351 @default.
• W2006485019 cites W2009544118 @default.
• W2006485019 cites W2022892498 @default.
• W2006485019 cites W2029838482 @default.
• W2006485019 cites W2030684792 @default.
• W2006485019 cites W2034756115 @default.
• W2006485019 cites W2036960973 @default.
• W2006485019 cites W2065718653 @default.
• W2006485019 cites W2079264209 @default.
• W2006485019 cites W2090679855 @default.
• W2006485019 cites W2159141356 @default.
• W2006485019 cites W2171919403 @default.
• W2006485019 cites W2188518053 @default.
• W2006485019 cites W2803573053 @default.
• W2006485019 cites W2950949341 @default.
• W2006485019 doi "https://doi.org/10.1016/j.chemosphere.2004.08.029" @default.
• W2006485019 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/15504471" @default.
• W2006485019 hasPublicationYear "2004" @default.
• W2006485019 type Work @default.
• W2006485019 sameAs 2006485019 @default.
• W2006485019 citedByCount "21" @default.
• W2006485019 countsByYear W20064850192012 @default.
• W2006485019 countsByYear W20064850192013 @default.
• W2006485019 countsByYear W20064850192014 @default.
• W2006485019 countsByYear W20064850192017 @default.
• W2006485019 countsByYear W20064850192019 @default.
• W2006485019 countsByYear W20064850192020 @default.
• W2006485019 countsByYear W20064850192021 @default.
• W2006485019 countsByYear W20064850192022 @default.
• W2006485019 crossrefType "journal-article" @default.
• W2006485019 hasAuthorship W2006485019A5001364873 @default.
• W2006485019 hasAuthorship W2006485019A5031648040 @default.
• W2006485019 hasAuthorship W2006485019A5032971728 @default.
• W2006485019 hasAuthorship W2006485019A5048246567 @default.
• W2006485019 hasAuthorship W2006485019A5058846543 @default.
• W2006485019 hasAuthorship W2006485019A5062941929 @default.
• W2006485019 hasAuthorship W2006485019A5063663504 @default.
• W2006485019 hasConcept C121332964 @default.
• W2006485019 hasConcept C123669783 @default.
• W2006485019 hasConcept C148898269 @default.
• W2006485019 hasConcept C161790260 @default.
• W2006485019 hasConcept C178790620 @default.
• W2006485019 hasConcept C184651966 @default.
• W2006485019 hasConcept C185592680 @default.
• W2006485019 hasConcept C2778077586 @default.
• W2006485019 hasConcept C2779679103 @default.
• W2006485019 hasConcept C41008148 @default.
• W2006485019 hasConcept C62520636 @default.
• W2006485019 hasConcept C65165184 @default.
• W2006485019 hasConcept C66882249 @default.
• W2006485019 hasConcept C75473681 @default.
• W2006485019 hasConcept C76155785 @default.
• W2006485019 hasConcept C82685317 @default.
• W2006485019 hasConcept C93391505 @default.
• W2006485019 hasConcept C97355855 @default.
• W2006485019 hasConceptScore W2006485019C121332964 @default.
• W2006485019 hasConceptScore W2006485019C123669783 @default.
• W2006485019 hasConceptScore W2006485019C148898269 @default.
• W2006485019 hasConceptScore W2006485019C161790260 @default.
• W2006485019 hasConceptScore W2006485019C178790620 @default.
• W2006485019 hasConceptScore W2006485019C184651966 @default.
• W2006485019 hasConceptScore W2006485019C185592680 @default.
• W2006485019 hasConceptScore W2006485019C2778077586 @default.
• W2006485019 hasConceptScore W2006485019C2779679103 @default.
• W2006485019 hasConceptScore W2006485019C41008148 @default.
• W2006485019 hasConceptScore W2006485019C62520636 @default.
• W2006485019 hasConceptScore W2006485019C65165184 @default.
• W2006485019 hasConceptScore W2006485019C66882249 @default.
• W2006485019 hasConceptScore W2006485019C75473681 @default.
• W2006485019 hasConceptScore W2006485019C76155785 @default.
• W2006485019 hasConceptScore W2006485019C82685317 @default.
• W2006485019 hasConceptScore W2006485019C93391505 @default.
• W2006485019 hasConceptScore W2006485019C97355855 @default.
• W2006485019 hasIssue "9" @default.
• W2006485019 hasLocation W20064850191 @default.
• W2006485019 hasLocation W20064850192 @default.
• W2006485019 hasOpenAccess W2006485019 @default.
• W2006485019 hasPrimaryLocation W20064850191 @default.
• W2006485019 hasRelatedWork W1967693895 @default.
• W2006485019 hasRelatedWork W2202470948 @default.
• W2006485019 hasRelatedWork W2346460465 @default.
• W2006485019 hasRelatedWork W2368751403 @default.
• W2006485019 hasRelatedWork W2380312555 @default.

• next