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- W2006502511 abstract "Abstract Two dithienylpyrroles based on azo dyes, namely 2,5′-dimethyl-[4-(2,5-di-thiophen-2-yl-pyrrol-1-yl)-phenyl]azobenzene (SNS-AB2) and 2,5′-dimethyloxy-[4-(2,5-di-thiophen-2-yl-pyrrol-1-yl)-phenyl]azobenzene (SNS-AB3), were synthesized and their corresponding polymers (PSNS-AB2 and PSNS-AB3) were successfully obtained via electropolymerization. The monomers have lower oxidation potentials (0.75 V and 0.80 V vs. Ag/AgCl for SNS-AB2 and SNS-AB3, respectively) when compared to their analogous. Both monomers exhibited photoisomerism properties under irradiation at 360 nm. During the irradiation process, for example, the color of SNS-AB3 changes from yellow to greenish yellow. The electroactive polymer films have well defined and reversible redox couples with a good cycle stability in both aqueous and organic solutions. The polymer films also exhibited electrochromic behaviors; color changes from yellowish green to dark green for the PSNS-AB2 ( λ max = 435 nm and E g = 2.31 eV) and from mustard color to green for PSNS-AB3 ( λ max = 430 nm and E g = 2.34 eV). Furthermore, the soluble polymers demonstrated different hues of yellow and green colors." @default.
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- W2006502511 date "2009-02-01" @default.
- W2006502511 modified "2023-10-01" @default.
- W2006502511 title "Electrochemical and optical properties of new soluble dithienylpyrroles based on azo dyes" @default.
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- W2006502511 doi "https://doi.org/10.1016/j.electacta.2008.09.067" @default.
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