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• W2006551498 abstract "The complexation between Th(IV) and acetate in 1.05 mol kg−1 NaClO4 was studied at variable temperatures (10, 25, 40, 55 and 70 °C). The formation constants of five successive complexes, Th(Ac)j(4−j)+ where Ac = CH3COO− and j = 1–5, and the molar enthalpies of complexation were determined by potentiometry and calorimetry. Extended X-ray absorption fine structure spectroscopy (EXAFS) provided additional information on the complexes in solution. The effect of temperature on the stability of the complexes is discussed in terms of the electrostatic model." @default.
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• W2006551498 date "2004-01-01" @default.
• W2006551498 modified "2023-09-23" @default.
• W2006551498 title "Complexation of thorium(iv) with acetate at variable temperatures" @default.
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• W2006551498 doi "https://doi.org/10.1039/b407389d" @default.
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