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- W2006607130 abstract "The silanol TsiSiMe(C 6 H 4 Me- p)OH (Tsi = (Me 3 Si) 3 C) has been shown to react with some acid chlorides RCOCl (R = Me, Et, ClCH 2 ) and acetic acid anhydride (MeCO) 2 O to give the related carboxylates TsiSiMe(C 6 H 4 Me- p)OCOR. It also reacts with 4-O 2 NC 6 H 4 COCl and a mixture of Cl 2 CHCOCl and AlCl 3 to give TsiSiMe[C 6 H 3 -3-(CO-C 6 H 4 NO 2 -p)-4-Me]OCOC 6 H 4 NO 2 -p and TsiSiMe[C 6 H 3 -3-(COCHCl 2 - 4-Me)]OCOCHCl 2 respectively. The reaction of the silanol TsiSiMe(C 6 H 4 OMe-p)OH with acid chloride RCOCl (R = Me or Et) gives TsiSiMeClOCOR and TsiSiMe(RCO)OCOR, while in the presence of pyridine gives the normal carboxylate TsiSiMe(C 6 H 4 OMe-p)OCOR." @default.
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- W2006607130 date "2003-01-01" @default.
- W2006607130 modified "2023-09-25" @default.
- W2006607130 title "Reactions of the Highly Sterically Hindered Silanols (Me3Si)3CSiMe(C6H4R-p)OH with acid chlorides" @default.
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- W2006607130 doi "https://doi.org/10.3184/030823403103172869" @default.
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