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• W2006623193 abstract "Spherical (Ni0.5Mn0.5)(OH)2 with different secondary particle size (3 μm, 10 μm in diameter) was synthesized by co-precipitation method. Mixture of the prepared hydroxide and lithium hydroxide was calcined at 950 °C for 20 h in air. X-ray diffraction patterns revealed that the prepared material had a typical layered structure with R3¯m space group. Spherical morphologies with mono-dispersed powders were observed by scanning electron microscopy. It was found that the layered Li[Ni0.5Mn0.5]O2 delivered an initial discharge capacity of 148 mAh g−1 (3.0–4.3 V) though the particle sizes were different. Li[Ni0.5Mn0.5]O2 having smaller particle size (3 μm) showed improved area specific impedance due to the reduced Li+ diffusion path, compared with that of Li[Ni0.5Mn0.5]O2 possessing larger particle size (10 μm). Although the Li[Ni0.5Mn0.5]O2 (3 μm) was electrochemically delithiated to Li0.39[Ni0.5Mn0.5]O2, the resulting exothermic onset temperature was around 295 °C, of which the value is significantly higher than that of highly delithiated Li1−δCoO2 (∼180 °C)." @default.
• W2006623193 created "2016-06-24" @default.
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• W2006623193 date "2008-08-01" @default.
• W2006623193 modified "2023-10-16" @default.
• W2006623193 title "Particle size effect of Li[Ni0.5Mn0.5]O2 prepared by co-precipitation" @default.
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• W2006623193 doi "https://doi.org/10.1016/j.electacta.2008.02.106" @default.
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