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- W2006644046 abstract "Hydrolysis rate constants of six-, eight-, twelve- and sixteen-membered inorganic cyclophosphates at various acid strengths at 40°C were determined. Six-membered cyclotriphosphate was the most rapidly hydrolyzed at almost all acid concentrations, as a result of its interaction with hydrogen ion, and strain in the six-membered ring structure. The hydrolysis rate of the cyclophosphate which has a stronger affinity with hydrogen ions was faster than that of others. Binding of hydrogen ions renders the phosphorus atoms more susceptible to nucleophilic attack by water molecules." @default.
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- W2006644046 title "Hydrolysis reaction of inorganic cyclophosphates at various acid strengths" @default.
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- W2006644046 doi "https://doi.org/10.1016/s0277-5387(00)81020-7" @default.
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