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- W2006689698 abstract "Polymers bearing at the end of side chains acidobasic indicator moieties exhibiting a solvatochromic absorption band were prepared by a polymeranalogous reaction of copolymers N-(2-hydroxy propyl) methacrylamide-N-methacryloylated 4-nitrophenyl ester ω-aminoacids with 1-(2-aminoethyl)-4-(4-hydroxystyryl)pyridinium bromide. It was found that p K a of reporters bound at a medium long side chain (six methylene groups) is close to p K a of a low-molecular model compound, while p K a of a reporter bound close to the polymer backbone is approximately by one p K a unit higher. Changes in the p K a value of the reporters are discussed in connection with a change in the polarity of microenvironment of polymer chains." @default.
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- W2006689698 date "1990-01-01" @default.
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- W2006689698 title "Microenvironment of polymer chains in solution: pKa of indicators bound to the polymer chain" @default.
- W2006689698 doi "https://doi.org/10.1135/cccc19902226" @default.
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