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• W2006711174 abstract "The article reports on the unique manipulation of the acid-catalyzed reaction of [2-aminoporphyrinato(2-)]nickel with formaldehyde to form selectively either the symmetric Tröger’s base or the asymmetric spiro Tröger’s base bis(metalloporphyrin) derivative. The reaction is driven by the choice of acid catalyst, formaldehyde source, and particularly, solvent, to give a mixture of both derivatives in preparative yields of about 90%, or to give selectively one of the derivatives in a yield of about 60%." @default.
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• W2006711174 date "2012-11-01" @default.
• W2006711174 modified "2023-10-07" @default.
• W2006711174 title "Selective formation of either Tröger’s base or spiro Tröger’s base derivatives from [2-aminoporphyrinato(2-)]nickel by choice of reaction conditions" @default.
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• W2006711174 doi "https://doi.org/10.1016/j.tetlet.2012.08.097" @default.
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