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- W2006736106 abstract "Abstract Two novel methods are proposed for the synthesis of σ-ethynylmetal carbonyl derivatives. Firstly, reaction of metal carbonyl anions with haloacetylenes, and secondly, reaction of metal carbonyl anions with mixed ethynylphosphonium salts. The former method gave a 40% yield of C 5 H 5 (CO) 3 CrCCC 6 H 5 for the first time. The latter method is prefered for the synthesis of C 5 H 5 (CO) 3 MCCC 6 H 5 (M = Mo, W) giving 45–54% of the σ-phenylethynyl derivatives." @default.
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- W2006736106 date "1979-02-01" @default.
- W2006736106 modified "2023-09-28" @default.
- W2006736106 title "New methods of synthesis of σ-ethynylmetal carbonyl derivatives" @default.
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- W2006736106 doi "https://doi.org/10.1016/s0022-328x(00)91636-x" @default.
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