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- W2006792009 abstract "Abstract The motional non-equivalence in a deuteriated -CD2-segment of a hydrocarbon chain near a chiral carbon atom has been investigated in a series of nematic and cholesteric phases. The deuterium nuclear magnetic resonance signals show the number of non-equivalent motions as equal to the number of different quadrupole doublet splittings. It is shown that a necessary but not sufficient condition for motional non-equivalence is the presence of a chiral carbon. The chiral carbon is not sufficient because in some cases the two quadrupole doublets may accidentally overlap. The composition of a number of nematic and cholesteric meso-phases has been located and recorded.The non-equivalence is affected to a large extent by the protonation of the chiral head group, showing that head group anchoring is changed in this chemical modification." @default.
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- W2006792009 date "1984-12-01" @default.
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- W2006792009 title "The Aqueous Lyotropic Analogues of Thermotropic Nematics and Cholesterics" @default.
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- W2006792009 doi "https://doi.org/10.1080/00268948408071670" @default.
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