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- W2006796844 abstract "The temperature dependence of selected low-wavenumber (< 200 cm(-1)) Raman bands was studied for the different crystalline phases (α-, β-, γ-) of glycine--the simplest possible building block of a biomolecule. The temperature dependence of the frequencies of vibrational modes deviates from the theoretical expectation based on the assumption of cubic anharmonicity. Although relatively small, this deviation was observed above 250 K for all the three polymorphs. This finding was discussed in relation to the dynamical transition phenomenon, observed in variety of biomolecules in the range 200-250 K. The similarity of the temperatures suggests, that the origin of the dynamical transition phenomenon can be related to intrinsic conformational states of biomolecules, while water serves rather as a plasticizer or a structure organizer." @default.
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- W2006796844 date "2011-01-24" @default.
- W2006796844 modified "2023-09-27" @default.
- W2006796844 title "Raman study of low-frequency modes in three glycine polymorphs" @default.
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- W2006796844 doi "https://doi.org/10.1063/1.3524342" @default.
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