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• W2006799080 endingPage "7540" @default.
• W2006799080 startingPage "7531" @default.
• W2006799080 abstract "Ultrafast electron transfer was studied for a series of metalloporphyrin/bipyridinium complexes in aqueous solution, using laser excitation in the Soret or Q-bands of the porphyrin. Electron transfer occurred before electronic and vibrational relaxation of the initial excited state. This allowed for a thorough investigation of the dependence of electron transfer rate constants on the driving force and the nature of the product state. The driving force dependence showed that electron transfer from the S2 state occurred to an electronically excited radical pair state, and the present results provide the most direct evidence to date for the formation of such states in photoinduced electron transfer reactions. We also found that subsequent recombination of the radical pair produced vibrationally excited ground states; the excess energy of the radical pair generated from the initial state is not completely dissipated during the lifetime of the radical pair. The porphyrin/bipyridinium complexes where recombination lies deeper in the Marcus inverted region show less formation of unrelaxed ground states, contrary to what is expected from equilibrium electron transfer theories. Instead, the rate of the electron transfer, which competes with vibrational relaxation, was the main parameter controlling the relative yield of unrelaxed ground states within this series of complexes." @default.
• W2006799080 created "2016-06-24" @default.
• W2006799080 creator A5052221113 @default.
• W2006799080 creator A5053275875 @default.
• W2006799080 date "2015-04-01" @default.
• W2006799080 modified "2023-10-18" @default.
• W2006799080 title "Ultrafast Electron Transfer Dynamics in a Series of Porphyrin/Viologen Complexes: Involvement of Electronically Excited Radical Pair Products" @default.
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• W2006799080 doi "https://doi.org/10.1021/jp5113119" @default.
• W2006799080 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/25766332" @default.
• W2006799080 hasPublicationYear "2015" @default.
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