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- W2006810977 abstract "The interaction between poly (I) and poly (C) in acid medium has been studied by potentiometric titration, mixing curves and thermal denaturation. Phase diagramms as a function of ionic strength, pH, and temperature have been established. From these data it is shown that the acid titration of the complex poly (I) · poly (C) passes through a triple-stranded intermediate poly (I) · poly (C) · poly (C+) to yield finally the protonated double-helical complex poly (I) · poly (C+). The mixing curves indicate the sole presence of the three-stranded complex in the intermediate zone. On the basis of the pK's the coexistence between the three-stranded complex with the neighboring double-stranded structure is demonstrated in a narrow rang of pH and ionic strength. The geometry of the base arrangements, their conformation and the sense of the strands are discussed in the light of the data presented. A Hoogsteen-type pairing between the bases for poly (I) · poly (C+) is favored, although the reverse Hoogsteen pair cannot be excluded." @default.
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- W2006810977 date "1969-09-01" @default.
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- W2006810977 title "Polynucléotides protonés. VII. Transitions thermiques entre differents complexes de l'acide polyinosinique et de l'acide polycytidylique en milieu acide" @default.
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- W2006810977 doi "https://doi.org/10.1002/bip.1969.360080307" @default.
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