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- W2006817532 abstract "The reduction behaviors of the supported platinum–iron catalysts and their comparison with supported iron catalysts were studied by TPR (temperature-programmed reduction)–in situ 57Fe MBS (Mössbauer spectroscopy). The results indicated that the TPR processes of all Fe-containing catalysts were different from that of bulk α-Fe2O3. There were interactions between Pt, Fe and the γ-Al2O3 or SiO2 support for the Pt–Fe/γ-Al2O3 and Pt–Fe/SiO2 catalysts. All the iron-containing catalysts show that Fe3+ was highly dispersed on the support (γ-Al2O3 and SiO2) before reduction. No Fe0 was found in the reduction processes. The Fe3+ was reduced to Fe2+ in tetrahedral vacancy first for the reduction of the Pt–Fe/γ-Al2O3 catalyst. No Fe2+ in octahedral vacancy was found in the reduction of the Pt–Fe/SiO2 catalyst. Adding Pt to Fe/support (γ-Al2O3 or SiO2) could promote the reduction of the Fe species." @default.
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- W2006817532 date "1999-02-01" @default.
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- W2006817532 title "A study on reduction behaviors of the supported platinum–iron catalysts" @default.
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