Matches in SemOpenAlex for { <https://semopenalex.org/work/W2006836906> ?p ?o ?g. }
- W2006836906 endingPage "8363" @default.
- W2006836906 startingPage "8355" @default.
- W2006836906 abstract "We describe the synthesis and characterization of six bridged molecular gyroscopes with m-alkoxy-substituted trityl stators and dialkynylphenylene rotators. All of the bridged molecular gyroscopes were synthesized convergently to form the phenolic stator–rotator framework, while the alkyl and benzophenone bridges were installed in one step by relatively efficient one-pot reactions to form macrocyclic diether or diester linkages. The isolated yield per bond-forming reaction varied from ca. 42% to 80%, with one exception where macrocyclization failed to produce the desired product. The molecular structure and crystal packing of each of the bridged molecular gyroscopes were determined via single crystal X-ray diffraction. Like most molecular gyroscopes with open topologies previously studied, the singly bridged structures pack by interdigitating one trityl stator in one molecule next to the rotator of an adjacent molecule in the lattice. In contrast, the triply bridged molecular gyroscopes were found to pack in lamellar sheets that prevent the rotator–stator interdigitation of adjacent molecules. However, solvent molecules and conformationally flexible bridges tend to fill in the packing volume by collapsing next to the rotator or by extending one of their bridges into the cavity of a neighboring molecule." @default.
- W2006836906 created "2016-06-24" @default.
- W2006836906 creator A5037851737 @default.
- W2006836906 creator A5055256920 @default.
- W2006836906 creator A5070479287 @default.
- W2006836906 date "2011-09-26" @default.
- W2006836906 modified "2023-09-27" @default.
- W2006836906 title "Synthesis of Bridged Molecular Gyroscopes with Closed Topologies: Triple One-Pot Macrocyclization" @default.
- W2006836906 cites W1559264985 @default.
- W2006836906 cites W1658488588 @default.
- W2006836906 cites W1965280541 @default.
- W2006836906 cites W1981936908 @default.
- W2006836906 cites W1984723052 @default.
- W2006836906 cites W1991752220 @default.
- W2006836906 cites W1992094850 @default.
- W2006836906 cites W1993307169 @default.
- W2006836906 cites W1995846141 @default.
- W2006836906 cites W1996613577 @default.
- W2006836906 cites W2000355243 @default.
- W2006836906 cites W2006813260 @default.
- W2006836906 cites W2011105629 @default.
- W2006836906 cites W2013548035 @default.
- W2006836906 cites W2028138737 @default.
- W2006836906 cites W2028173740 @default.
- W2006836906 cites W2031907429 @default.
- W2006836906 cites W2033184864 @default.
- W2006836906 cites W2034196396 @default.
- W2006836906 cites W2037749244 @default.
- W2006836906 cites W2050074677 @default.
- W2006836906 cites W2051096232 @default.
- W2006836906 cites W2051553980 @default.
- W2006836906 cites W2056191603 @default.
- W2006836906 cites W2058912931 @default.
- W2006836906 cites W2064866349 @default.
- W2006836906 cites W2068057338 @default.
- W2006836906 cites W2074748008 @default.
- W2006836906 cites W2075470589 @default.
- W2006836906 cites W2080501396 @default.
- W2006836906 cites W2084040958 @default.
- W2006836906 cites W2084912049 @default.
- W2006836906 cites W2085446754 @default.
- W2006836906 cites W2085567753 @default.
- W2006836906 cites W2086660115 @default.
- W2006836906 cites W2088015613 @default.
- W2006836906 cites W2094992955 @default.
- W2006836906 cites W2098962238 @default.
- W2006836906 cites W2099392831 @default.
- W2006836906 cites W2114396226 @default.
- W2006836906 cites W2122220082 @default.
- W2006836906 cites W2147440332 @default.
- W2006836906 cites W2148405700 @default.
- W2006836906 cites W2149381236 @default.
- W2006836906 cites W2151826672 @default.
- W2006836906 cites W2162560681 @default.
- W2006836906 cites W2332763359 @default.
- W2006836906 cites W4255519670 @default.
- W2006836906 doi "https://doi.org/10.1021/jo201513y" @default.
- W2006836906 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/21913700" @default.
- W2006836906 hasPublicationYear "2011" @default.
- W2006836906 type Work @default.
- W2006836906 sameAs 2006836906 @default.
- W2006836906 citedByCount "36" @default.
- W2006836906 countsByYear W20068369062012 @default.
- W2006836906 countsByYear W20068369062013 @default.
- W2006836906 countsByYear W20068369062014 @default.
- W2006836906 countsByYear W20068369062015 @default.
- W2006836906 countsByYear W20068369062016 @default.
- W2006836906 countsByYear W20068369062017 @default.
- W2006836906 countsByYear W20068369062018 @default.
- W2006836906 countsByYear W20068369062019 @default.
- W2006836906 countsByYear W20068369062020 @default.
- W2006836906 countsByYear W20068369062021 @default.
- W2006836906 countsByYear W20068369062022 @default.
- W2006836906 crossrefType "journal-article" @default.
- W2006836906 hasAuthorship W2006836906A5037851737 @default.
- W2006836906 hasAuthorship W2006836906A5055256920 @default.
- W2006836906 hasAuthorship W2006836906A5070479287 @default.
- W2006836906 hasConcept C178790620 @default.
- W2006836906 hasConcept C185592680 @default.
- W2006836906 hasConcept C2780263894 @default.
- W2006836906 hasConcept C32909587 @default.
- W2006836906 hasConcept C71240020 @default.
- W2006836906 hasConcept C8010536 @default.
- W2006836906 hasConceptScore W2006836906C178790620 @default.
- W2006836906 hasConceptScore W2006836906C185592680 @default.
- W2006836906 hasConceptScore W2006836906C2780263894 @default.
- W2006836906 hasConceptScore W2006836906C32909587 @default.
- W2006836906 hasConceptScore W2006836906C71240020 @default.
- W2006836906 hasConceptScore W2006836906C8010536 @default.
- W2006836906 hasIssue "20" @default.
- W2006836906 hasLocation W20068369061 @default.
- W2006836906 hasLocation W20068369062 @default.
- W2006836906 hasOpenAccess W2006836906 @default.
- W2006836906 hasPrimaryLocation W20068369061 @default.
- W2006836906 hasRelatedWork W1974496386 @default.
- W2006836906 hasRelatedWork W2007535035 @default.
- W2006836906 hasRelatedWork W2082989531 @default.
- W2006836906 hasRelatedWork W2087761197 @default.