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- W2006850007 abstract "Abstract The influence of sticker groups (COOH) on the adhesion energy (G 1C) of a model carboxylated polybutadiene-amine terminated silane modified aluminum (cPBD-AIS) interface was examined using a T-peel test. An optimal COOH concentration of around 0.5 mol% was observed. At this concentration the interface possessed a maximum peel energy of 600 J/m2, which is approximately equal to the cohesive peel energy of PBD. The adhesion strength of the interface increased as the interaction parameter (°CHP-S) between COOH and the solid substrate increased. Additionally, G IC was strongly dependent on the annealing time, resulting from slow surface reorganization processes. The interface structure was explored using the self-consistent field lattice model (SCFLM) developed by Theodorou. An interphase region adjacent to the solid substrate was found as a consequence of a gradient in chain connectivity and a strong sticker group segregation near the solid surface. The modeling study provided information about how the interphase structure changed with φ and °CHP-S, explaining the experimental results well." @default.
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- W2006850007 date "1999-10-01" @default.
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- W2006850007 title "Adhesion at Polymer-Solid Interfaces: Influence of Sticker Groups on Structure, Chain Connectivity and Strength" @default.
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- W2006850007 doi "https://doi.org/10.1080/00218469908014848" @default.
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