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- W2006863346 abstract "Die Verbindung Ba2EuIrO6 wurde einkristallin mit Hilfe einer BaCl2Schmelze dargestellt und röntgenographisch untersucht. Sie kristallisiert hexagonal, Raumgruppe D6h4−P63/mmc mit a = 5,9159 Å; c = 14,7440 Å, Z = 3. Die 6L-Perowskitstruktur mit der Sequenz (h.c.c.)2 weist flächenverknüpfte Oktaederdoppel auf, die statistisch veteilt 0,75 Ir5+ und 0,25 Eu3+ enthalten. Die (Eu/Ir)2O9-Gruppen sind über Ecken mit EuO6-Einzeloktaedern zu einem dreidimensionalen Gerüst verknüpft. The compound Ba2EuIrO6 was prepared by solid state reaction (BaCl2 flux) and investigated by the X-ray single crystal technique. It crystallizes with hexagonal symmetry: space group D6h4−P63/mmc, a = 5.9159 Å; c = 14.7440 Å, Z = 3. The 6L-perovskite-like structure shows a sequence (h.c.c.)2 and face-connected octahedra, statistically occupied by 0.75 Ir5+ and 0.25 Eu3+. The (Eu/Ir)2O9 groups and isolated EuO6 octahedra form a three-dimensional network." @default.
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- W2006863346 date "1990-06-01" @default.
- W2006863346 modified "2023-10-16" @default.
- W2006863346 title "Ba2EuIrO6—eine einkristalluntersuchung an einer 6L-perowskitstapelvariante" @default.
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- W2006863346 doi "https://doi.org/10.1016/0022-5088(90)90307-6" @default.
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