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• W2006868401 abstract "Preparation of polyimide composite membranes by the vapor deposition and polymerization method (VDP) has been investigated. 3,3′,4,4′-Benzophenon tetracarboxylic dianhydride (BTDA), and 4,4′-diaminodiphenyl ether (ODA) were used as monomers. BTDA and ODA were simultaneously deposited on substrates in a vacuum of 10−6 Torr, where the molar ratio of BTDA to ODA is unity. The deposition layer was converted from polyamide acid to polyimide by heating at 200°C for 3 h in an ordinary vacuum oven. The substrates of the composite membranes used were polymide asymmetric membranes. They were prepared by the phase inversion process from the casting solution of 24 wt% of commercial polyimide (PI-2080) and 76 wt% of N,N'-dimethylacetamide. The thickness of the deposited layer formed was ca. 0.05–0.4 μm. Separation performance of polyimide composite membranes were measured by pervaporation method using a 95 vol% aqueous ethanol solution. A composite membrane with a deposition layer thicker than 0.2 μm exhibited a separation factor of 1300." @default.
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• W2006868401 date "1997-12-01" @default.
• W2006868401 modified "2023-10-10" @default.
• W2006868401 title "Preparation and pervaporation performance of polyimide composite membrane by vapor deposition and polymerization (VDP)" @default.
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• W2006868401 doi "https://doi.org/10.1016/s0376-7388(97)00163-4" @default.
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