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- W2006911251 abstract "We introduce a new sensing polymer system for detection of volatile organic compounds (VOCs) based on the optical response of polystyrene (PS) films doped with julolidine fluorescent molecular rotors (FMRs). The julolidine FMRs exhibited viscosity-dependent changes in the fluorescence intensity, that was enhanced when glycerol was added to ethanol solutions and when they were dispersed in PS films. Thus, reduction in medium mobility slowed down internal motions and allowed for a major radiative decay pathway. The FMR/PS films were exposed to several VOCs, and showed a significant decrease in fluorescence emission when exposed to chloroform, whereas a negligible variation in their emission occurred when methanol was utilized. This vapour sensing behaviour was much more evident when a perfluorodecyl chain was linked to the julolidine core being the molecule segregated at the film surface. This responsive behaviour was affected by solvent composition and its reproducible response was easily determined by luminescence experiments." @default.
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- W2006911251 date "2015-02-01" @default.
- W2006911251 modified "2023-10-07" @default.
- W2006911251 title "Julolidine fluorescent molecular rotors as vapour sensing probes in polystyrene films" @default.
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- W2006911251 doi "https://doi.org/10.1016/j.dyepig.2014.07.025" @default.
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