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- W2006922017 abstract "Silicalite crystals were synthesized on various kinds of substrates. It was found that crystals on a polymer substrate (poly(tetrafluoroethylene-perfluoroalkylvinyl ether)) with a smooth surface grew into zeolite films by sliding on the substrate surface, whereas those on a silica glass substrate grew by anchoring to certain positions. To examine the mechanical strength of the anchoring of zeolitic coatings, these crystals were calcinated together with the substrates. The crystals did not get detached from the substrate surface, indicating a strong interaction between the crystals and the substrate. The secondary growth of small crystals in the synthesis mixture was also investigated, and the possibility of forming a compact zeolite film by promoting the nucleation of small crystals around seed crystals was confirmed." @default.
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- W2006922017 date "2000-07-01" @default.
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- W2006922017 title "Direct observation of the formation process of silicalite films on various substrates" @default.
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