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- W2006941595 abstract "Dehydrocoupling polymerization of phenylsilane with group 4 metallocene precatalysts Cp 2 MY 2 (M = Ti, Zr, Hf; Y = F, OPh, NMe 2 ) under comparable conditions has been examined. All nine title metallocenes produced polysilane products which ranged in molecular weight from 1100 to 4400 and exhibited ratios of linear to cyclic products from ~2 to 30. The highest molecular weight polysilanes observed for each metal were obtained from Cp 2 M(NMe 2 ) 2 and the highest percentage of linear polysilane was found with Cp 2 Hf(NMe 2 ) 2 . The near stoichiometric reactions of Cp 2 MY 2 with PhSiH 3 , PhMeSiH 2 , and Ph 2 MeSiH were monitored by 1 H, 19 F and 29 Si NMR spectroscopy and in all cases exchange products containing Si-Y were identified. Metal hydride species could be observed only with Cp 2 TiY 2 .Key words: metallocene, dehydrocoupling, polymerization, hydrosilanes, polysilane." @default.
- W2006941595 created "2016-06-24" @default.
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- W2006941595 date "2000-11-01" @default.
- W2006941595 modified "2023-10-16" @default.
- W2006941595 title "Dehydrocoupling reactions of hydrosilanes with group 4 metallocenes Cp<sub>2</sub>MY<sub>2</sub> (M = Ti, Zr, Hf; Y = F, OPh, NMe<sub>2</sub>)" @default.
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- W2006941595 doi "https://doi.org/10.1139/v99-237" @default.
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