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• W2006959531 endingPage "2873" @default.
• W2006959531 startingPage "2863" @default.
• W2006959531 abstract "A general strategy for the transformation of D-glucose into different 2-substituted (R)-4- hydroxy-cyclopent-2-enones is described. This has been illustrated by the synthesis of (R)-2-[(1,3-dithian-2-yl)methyl]-4-hydroxycyclopent-2-enone, (R)-2-benzyloxymethyl-4-hydroxycyclopent-2-enone, and (R)-2-allyl-4-hydroxycyclopent-2-enone, which are potential chiral synthons for prostaglandin E2, the antibiotic (–)-pentenomycin I, and the synthetic insecticide allethrin, respectively. The second chiral synthon was obtained by two different routes, one of them involving a novel palladium(0)-catalysed rearrangement of a vinyloxirane intermediate." @default.
• W2006959531 created "2016-06-24" @default.
• W2006959531 creator A5018644186 @default.
• W2006959531 creator A5052211113 @default.
• W2006959531 date "1990-01-01" @default.
• W2006959531 modified "2023-10-09" @default.
• W2006959531 title "A concise and general entry into (R)-4-hydroxy-2-substituted cyclopent-2-enones from<scp>D</scp>-glucose: chiral intermediates for the synthesis of PGE₂, (–)-pentenomycin I, and allethrin" @default.
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• W2006959531 doi "https://doi.org/10.1039/p19900002863" @default.
• W2006959531 hasPublicationYear "1990" @default.
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