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- W2006990134 abstract "K6Ta10.8O30 crystallizes in the tetragonal system with unit-cell dimensions a = 12.579(6), c = 3.978(2) Å, and space group P4mbm, z = 1. The calculated and measured densities are 7.04 and 7.00(2) g cm−3, respectively. The structure was solved using conventional methods; of 539 unique reflections measured by countermethods, 435 that obeyed the condition I ⩾ 3σ(I) were used in the least-squares refinement of the model to a conventional R of 0.038 (wR = 0.036). Basically, the structure is of the tetragonal tungsten bronze-type (K6Ta10.8O30 = 10 × K0.6Ta1.08O3) with the additional tantalum in nine-coordinate (tricapped trigonal prismatic) sites. The presence of the additional tantalum (Ta5+) enables this framework, frequently met for M6+ compounds, to attain electrical neutrality." @default.
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- W2006990134 date "1978-01-01" @default.
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- W2006990134 title "Crystal structures of some niobium and tantalum oxides. III K6Ta10.8O30—A partially “Filled” tetragonal tungsten bronze-like structure" @default.
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- W2006990134 doi "https://doi.org/10.1016/0022-4596(78)90083-x" @default.
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