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- W2006993340 abstract "• We report the vibronic and cation spectra of cis - and trans - m -chloroanisole. • Spectral features mainly result from substituent-sensitive and in-plane ring vibrations. • The chlorine substituent can influence the transition energy and molecular vibration. We apply the resonant two-photon ionization (R2PI) and mass-analyzed threshold ionization (MATI) techniques to record the vibronic and cation spectra of m -chloroanisole. The vibronic features appear in two series, built on 35,822 ± 2 and 35,868 ± 2 cm −1 , corresponding to the origins of the S 1 ← S 0 electronic transition ( E 1 ’s) of the two rotamers. Analysis of the MATI spectra gives the adiabatic ionization energies (IEs) of 67,645 ± 5 and 68,008 ± 5 cm −1 for these two isomeric species. Comparing these data with those of anisole, we find that the chlorine substitution at the meta position leads to a red shift in the E 1 and a blue shift in the IE. The observed R2PI and MATI bands mainly result from the in-plane ring deformation and substituent-sensitive bending vibrations of these species in the electronically excited S 1 and cationic ground D 0 states." @default.
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- W2006993340 date "2013-11-01" @default.
- W2006993340 modified "2023-10-17" @default.
- W2006993340 title "Rotamers of m-chloroanisole studied by two-color resonant two-photon mass-analyzed threshold ionization spectroscopy" @default.
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- W2006993340 doi "https://doi.org/10.1016/j.chemphys.2013.08.013" @default.
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