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- W2007000918 abstract "The electrochemical reduction on mercury of a series of α, α-dibromoalkanes was studied at low cathodic potentials in aprotic media. 1,4-dibromobutane and 1,5-dibromopentane yielded solid alkyl-mercury compounds, the structures of which were established as being polymeric and of the general type R-Hg-(R-Hg)n-R (R alkyl). Proper adjustment of the electrochemical parameters allowed very high current efficiencies for the syntheses. The results obtained for 1,4-dibromobutane, combined with those already existing in the literature, permitted the formation of a general mechanism for the process." @default.
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- W2007000918 date "1977-03-01" @default.
- W2007000918 modified "2023-09-23" @default.
- W2007000918 title "Synthetic and mechanistic aspects of the electrochemical formation of polimeric alkyl-mercury compounds" @default.
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- W2007000918 doi "https://doi.org/10.1016/0013-4686(77)85064-0" @default.
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