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• W2007009318 abstract "The Mössbauer spectra and magnetic susceptibilities have been obtained for a series of Prussian Blue analogues of general formula MjA[MB(CN)6]k·mH2O where MA and MB are transition metal ions, j and k vary with the oxidation states of MA and MB and m typically has values from 8 to 14. The compounds were prepared from the hexacyano acids or with large quaternary ammonium counterions and are therefore not contaminated with alkali cations. In each analogue, A or B is iron and the second metal is Mn, Cu, Co, Cr or Ru. In each case it was possible to assign the site (A or B), oxidation state and spin state to each transition metal ion. This group of compounds are all class II mixed valence species from their colours, but do not show evidence of linkage isomerism or redox changes compared to the starting materials. The Mössbauer linewidths are consistent with the Ludi model of Prussian Blue." @default.
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• W2007009318 date "1984-01-01" @default.
• W2007009318 modified "2023-09-24" @default.
• W2007009318 title "An investigation of Prussian Blue analogues by Mössbauer spectroscopy and magnetic susceptibility" @default.
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• W2007009318 doi "https://doi.org/10.1016/s0277-5387(00)88049-3" @default.
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