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- W2007014049 abstract "Abstract The title subject is studied by galvanostatic E—t curves on 20 h stabilized passive tin electrodes in weakly alkaline phosphate solution (pH 9.5) at 25°C. These curves generally exhibit a small initial superpolarization ascribed to transient changes in the surface density of kinks ( s ) by the current density ( j ) applied. Obedience is found to the Cabrera—Mott equation for irreversible metal ion transfer from kink sites in the metal surface and to the oxide film. For the steady-growth kink density and the ion transfer valence, it is found that d log s /d log j = 0.5 and n = 2, respectively. No space-charge effect is seen in passive films growing at rates up to 100 μA cm −2 (the highest current applied)." @default.
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- W2007014049 date "1994-10-01" @default.
- W2007014049 modified "2023-09-24" @default.
- W2007014049 title "Anodic growth of passive films on tin" @default.
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- W2007014049 doi "https://doi.org/10.1016/0013-4686(94)e0173-w" @default.
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